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Journal Articles

Research on hydrogen safety technology utilizing the automotive catalyst

Ono, Hitomi*; Takenaka, Keisuke*; Kita, Tomoaki*; Taniguchi, Masashi*; Matsumura, Daiju; Nishihata, Yasuo; Hino, Ryutaro; Reinecke, E.-A.*; Takase, Kazuyuki*; Tanaka, Hirohisa*

E-Journal of Advanced Maintenance (Internet), 11(1), p.40 - 45, 2019/05

Journal Articles

Design concept of the precious-metal-free automotive catalyst using copper oxide and alloys

Nishihata, Yasuo; Tanaka, Hirohisa*; Mitachi, Senshu*; Kasai, Hideaki*

Kogyo Zairyo, 62(5), p.41 - 44, 2014/05

no abstracts in English

Journal Articles

Automotive catalysts with self-regeneration

Tanaka, Hirohisa*; Nishihata, Yasuo

Kogyo Zairyo, 50(13), p.35 - 38, 2002/12

no abstracts in English

Journal Articles

Immortal catalytic activity for cleaning up automotive emissions; Intelligent catalyst

Nishihata, Yasuo; Tanaka, Hirohisa*

SPring-8 Riyosha Joho, 7(6), p.359 - 363, 2002/11

Catalytic converters are widely applied to control automotive emissions, such as nitrogen oxides, carbon monoxide and unburned hydrocarbons. In actual catalysts, however, the catalytic activity deteriorates due to the particle growth of precious metals during vehicle use. An ageless catalyst is a kind of philosopher's stone in automotive engineering. Referring to the wisdom of ancient Indian philosophy and medical science, Ayur Veda, we have developed a new self-regenerating perovskite-based catalyst. The perovskite catalyst, LaFe$$_{0.57}$$Co$$_{0.38}$$Pd$$_{0.05}$$O$$_{3}$$, regenerates itself without any auxiliary treatment, in direct reaction to the natural fluctuation between reductive and oxidative atmospheres in the exhaust gas from state-of-the-art gasoline engines. As palladium reversibly moves back and forth between inside and outside of the perovskite crystal, the particle growth of palladium can be suppressed. Such a self-regeneration provides new insight into the development of future automotive catalyst, as an intelligent catalyst.

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